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Correspondence of the late James Watt on his discovery of the theory of the composition of water : with a letter from his son / edited with introductory remarks and an appendix by James Patrick Muirhead
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PHILOSOPHICAL TRANSACTIONS.

83

4. It appears that deplilogisticated water, or,which may be a better name for the basis of waterand air, the element you call humor, has a more powerful attraction for phlogiston than it has for latent heat, but that it cannot unite with it, at least not to the point of saturation, or to the total expul- sion of the heat, unless it be first made red-hot, ornearly so. The electric spark heats a portion of it red-hot, the attraction between the humor and the phlogiston takes place, and the heat which is let loose from this first portion heats a second, which operates in a like manner on the adjoining parti- cles, and so continually, until the whole is heated red-hot and decomposed. Why this attractiondoes not take place to the same degree in the com-mon temperature of the atmosphere, is a question Iam not yet able to solve; but it appears, that, insome circumstances, deplilogisticated air can unite, in certain degrees, with phlogiston, without being changed into water. Thus Dr. Priestley has found,that by taking clean filings of iron, which alone pro-duce only inflammable air of the purest kind, andmercurius calcinatus per se, which gives only thepurest dephlogisticated air, and exposing them toheat in the same vessel, he obtained neither dephlo-gisticated nor inflammable air, but in their place fixed air. Yet it is well known, that a mixtureof dephlogisticated and inflammable air will remainfor years in close vessels in the common heat of theatmosphere, without suffering any change, the mix-ture being as capable of deflagration at the end ofthat time as it was when first shut up. These facts