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ALCOHOL.— Alcoiiolometry. Tralles’ Tables.

127

Tralles’ Table II.—Concluded.

Per cent.,bwolume,n? absolutealcohol.

Spec. grav.of the liquidat 60°.

Decrease of spec. grav. at the indicated temperatureabove t>0°.

«5®

70°

75®

80®

85°

90®

95°

100°

0

0-9991

1

n

17

24

32

40

50

60

5

9919

1

11

18

25

33

42

51

62

10

9857

6

13

20

29

37

47

57

68

15

9802

7

15

25

34

44

55

67

79

20

9751

9

19

30

41

53

66

79

93

25

9700

11

24

36

50

63

78

93

109

30

9646

14

28

43

59

75

91

108

125

35

9583

17

33

50

68

86

104

122

141

40

9510

18

37

56

75

94

114

136

154

45

9427

20

40

60

80

101

122

143

154

50

9335

21

42

63

84

106

128

150

173

55

9234

22

43

65

87

109

132

155

178

60

9126

22

44

67

90

113

136

150

183

65

9013

22

45

68

92

115

138

162

187

70

8892

23

46

69

93

117

141

165

190

75

8765

23

46

70

94

119

143

167

192

80

8631

23

47

71

96

120

144

169

194

85

8488

24

48

72

96

121

145

170

195

90

8332

24

48

72

97

121

146

171

.196

A further objection to these tables is, that thespecific gravity of the mixtures of alcohol and waterat elevated or reduced temperatures is not the realbut the apparent density. The cause of this dis-crepancy is, that the glass or copper vessel in whichthe liquids are weighed are liable to expand orcontract with change of temperature,

Tralles constructed a third table, in order that thepercentage by volume in an alcoholic liquid mightbe ascertained from the more uniform arrangementof the numbers denoting the specific gravities.

In Table III. the densities are given of the severalmixtures from 30° to 85°, as ascertained by a glassinstrument; but these numbers, by the aid of theallowance, as seen in Table IV., can be made tocorrespond with the indications of a brass alcoholo-meter.

The necessity for using Table IV. arises fromthe discrepancy in the contraction or expansionof glass or brass at different temperatures, occasioning

Tralles’ Table III.

Per cent.

Specific gravity of the liquid, ascertained by glass instruments, at the indicated temperatures.

by volume.

30®

z:°

40°

45°

50*

00*

65°

70°

76”

81 P°

85®

0

•9994

•9997

■9997

•9998

•9997

•9994

•9991

•9987

•9981

■9976

•9970

■9962

5

9924

9926

9926

9925

9925

9922

9919

9915

9909

9903

9897

9889

10

9868

9869

9868

9867

9865

9861

9857

9852

9845

9839

9831

9823

15

9823

9822

9820

9817

9813

9807

9802

9796

9788

9779

9771

9761

20

9786

9782

9777

9772

9766

9759

9751

9743

9733

9723

9713

9701

25

9752

9745 •

9737

9729

9720

9709

9700

9690

9678

9666

9653

9640

30

9715

9705

9694

9683

9671

9658

9646

9633

9619

9605

9590

9574

35

9668

9655

9641

9627

9612

9598

9583

9567

9551

9535

9518

9500

40

9609

9594

9577

9560

9544

9527

9510

9493

9474

9456

9438

9419

45

9535

9518

9500

9482

9464

9445

9427

9408

9388

9369

9359

9329

50

9449

9431

9413

9393

9374

9354.

9335

9315

9294

9274

9253

9232

55

9354

9335

9316

9295

9275

9254

9234

9213

9192

S171

9250

9128

60

9249

9230

9210

9189

9168

9147

9126

9105

9083

9061

9039

9016

65

9140

9120

9099

9078

9056

9034

9013

8992

8909

8947

8924

8901

70

9021

9001

8980

8958

8936

8913

8892

8870

8847

8825

8801

8778

75

8896

8875

8854

8832

8810

8787

8765

8743

8720

8697

8673

8649

80

8764

8743

8721

8699

8676

8653

8631

8609

8585

8562

8538

8514

85

8623

8601

8579

8556

8533

8510

8488

8465

8441

8418

8394

8370

90

8469

8446

8423

8401

8379

8355

8332

8309

8285

8262

8238

8214

Tralles’ Table IV.

To be subtracted.

To be added.

30°

35°

40°

45°

50°

55"

60*

05°

70°

75°

80°

85®

•0005

•0004

■0003

•0002

•0002

•0001

-

•0001

•0002

•0002

■0003

•0004

variation in the density; hence these numbersmust be added or subtracted, as directed, accord-ing to the temperature, when a brass instrumentis employed.

It occurs that liquids are tested whose temperatureand specific gravity are intermediate between thoseinstanced in the preceding table, and in this case thecorresponding content of alcohol must be found bycalculation. To give an example:—Let it be supposedthat the specific gravity of an alcoholic solution hasbeen found by experiment to be '9320 at a tempera-ture of 72° Fahr. In the column under 70°, thespecific gravity '9388 is that which is next over theabove number, and in the column under 75° thegravity nearest to it is '9369, both of which exceed'9320—the former by '0068, and the latter by '0049.

The difference between these two numbers is '0019,which is the variation for 5°, or between 70° and

o ‘0019 ,

75 , and by dividing by 5, the quotient is ——, the

difference for each degree. As the temperature ofthe liquid under examination is 72°, or 2° over 70°,it is necessary to reduce the specific gravity to whatit would indicate were the liquid at 70°, by adding a„ '0019 , -0038

multiple of —g— by 2, or . = -0007|- to the

specific gravity obtained.—'9320—which would makeit '9327f, or omitting fractions, -9327. By referringto the table, will be seen in the horizontal columnopposite 45 per cent, of alcohol, and under 70°, thespecific gravity '9388, and in the same column, in a